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Chalcopyrite and chalcogenide crystals are investigated for optical rectification and electro-optic sampling. Broadband and narrowband terahertz radiation is produced using ZnGeP2, CdSiP2, and AgGaSe2 chalcopyrite crystals, as well as a BaGa4Se7 chalcogenide crystal. Broadband terahertz radiation is detected using a ZnGeP2 chalcopyrite crystal. We envision these crystal classes being used to generate and detect terahertz radiation in research and commercial applications.
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B. N. Carnio, E. Hopmann, K. T. Zawilski, P. G. Schunemann, A. Y. Elezzabi, "Chalcopyrite and chalcogenide crystals for terahertz radiation generation and detection," Proc. SPIE 11670, Nonlinear Frequency Generation and Conversion: Materials and Devices XX, 116700P (5 March 2021); https://doi.org/10.1117/12.2583847