Paper
1 July 1992 Effective rotational constants of a triatomic molecule
Sergei V. Petrov
Author Affiliations +
Proceedings Volume 1811, Tenth All-Union Symposium and School on High-Resolution Molecular Spectroscopy; (1992) https://doi.org/10.1117/12.131151
Event: Tenth All-Union Symposium and School on High Resolution Molecular Spectroscopy, 1991, Omsk, Russian Federation
Abstract
In this paper we examine the classical mechanics of rovibrational interaction in a model of triatomic molecules, in which a bending mode interacts with the three-dimensional molecular rotation. In the rigid bender model used, both bond lengths are assumed frozen, and rovibrational coupling occurs only via the dependence of rotational constants on the bending coordinate. Although several quantum-mechanical calculations of rovibrational states have been performed for low-lying excited states, the study of highly excited states necessitates a classical approach.
© (1992) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Sergei V. Petrov "Effective rotational constants of a triatomic molecule", Proc. SPIE 1811, Tenth All-Union Symposium and School on High-Resolution Molecular Spectroscopy, (1 July 1992); https://doi.org/10.1117/12.131151
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KEYWORDS
Molecules

3D modeling

Molecular interactions

Ions

Mechanics

Chemistry

Molecular spectroscopy

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