Kinetic spectroscopy of NCl

Anatoly V. Komissarov; Gerald C. Manke II; Steven J. Davis; Michael C. Heaven

doi:10.1117/12.384275

4 May 2000 Kinetic spectroscopy of NCl

Anatoly V. Komissarov, Gerald C. Manke II, Steven J. Davis, Michael C. Heaven

Proceedings Volume 3931, Gas, Chemical, and Electrical Lasers and Intense Beam Control and Applications; (2000) https://doi.org/10.1117/12.384275
Event: Symposium on High-Power Lasers and Applications, 2000, San Jose, CA, United States

Abstract

Metastable NCl(a¹(Delta) ) is a promising energy carrier for use in chemically driven iodine lasers. The present studies of NCl(a) kinetics and demonstration of a non- intrusive method for detecting NCl(X) were conducted in support of efforts to develop an NCl(a)/I laser system. Photolysis of ClN₃ by O₂, H₂, HCl, Cl₂ and ClN₃ were determined. The result were consistent with recent measurements made in a discharge flow system. NCl(X) was detected via transient absorption of the b-(chi) system. A CW ring dye laser was used to record a high-resolution spectrum of the origin band. Time resolved absorption measurements were used to examine the kinetics of NCl(X) formation and decay.

Citation Download Citation

Anatoly V. Komissarov, Gerald C. Manke II, Steven J. Davis, and Michael C. Heaven "Kinetic spectroscopy of NCl", Proc. SPIE 3931, Gas, Chemical, and Electrical Lasers and Intense Beam Control and Applications, (4 May 2000); https://doi.org/10.1117/12.384275

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