Room temperature rate constant for H+F2

Jiande Han; Gerald C. Manke II; Michael C. Heaven

doi:10.1117/12.465771

6 May 2002 Room temperature rate constant for H+F₂

Jiande Han, Gerald C. Manke II, Michael C. Heaven

Proceedings Volume 4631, Gas and Chemical Lasers and Intense Beam Applications III; (2002) https://doi.org/10.1117/12.465771
Event: High-Power Lasers and Applications, 2002, San Jose, California, United States

Abstract

The rate constants for H atom reactions with Cl₂ and F₂ have been measured by monitoring the loss rate of hydrogen atoms in the presence of excess [Cl₂] and [F₂] via time-resolved, laser-induced Lyman-a fluorescence. The rate constants for H + F₂ and H + Cl₂ were found to be 2.4 +/- 0.4 X 10^-12 and 2.52 +/- 0.18 X 10^-11 cm³ molecules^-1 s^-1, respectively. The result for H + F₂ is consistent with the recommendation of Baulch et. al. (J. Phys. Chem. Ref. Data 10 (suppl. 1) (1981)) and our k(H + Cl₂) value is consistent with the majority of previous measurements.

Citation Download Citation

Jiande Han, Gerald C. Manke II, and Michael C. Heaven "Room temperature rate constant for H+F₂", Proc. SPIE 4631, Gas and Chemical Lasers and Intense Beam Applications III, (6 May 2002); https://doi.org/10.1117/12.465771

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available