Development of carbazole and bipyridine copolymers as novel photorefractive materials

D. Bogdal; M. Pajda; Jan Pielichowski; André-Jean Attias; J. Fave

doi:10.1117/12.676785

9 June 2006 Development of carbazole and bipyridine copolymers as novel photorefractive materials

D. Bogdal, M. Pajda, Jan Pielichowski, André-Jean Attias, J. Fave

Author Affiliations +

Proceedings Volume 6252, Holography 2005: International Conference on Holography, Optical Recording, and Processing of Information; 62520K (2006) https://doi.org/10.1117/12.676785
Event: Holography 2005: International Conference on Holography, Optical Recording, and Processing of Information, 2005, Varna, Bulgaria

Abstract

Novel acrylate copolymer with carbazole pendant groups and derivatives of bipyridine as side chains were synthesized, in which derivatives of bipyridine as electro-optic chromophores and carbazolyl as photoconductive moiety were covalently linked on the acrylate backbone. 2-{9-Carbazolyl)ethyl methacrylate (CEM) and 2-methyl-acrylic acid 2-{4,4'-dimethyl-5'-[2-(5-methyl-thiophen-2-yl)-vinyl]-[2,2']bipyridinyl-5-yl}-ethyl ester (BiPy) were synthesized and then copolymerized to give (99:1), (98:2), and (92:8 mol/mol) CEM/BiPy copolymers. Solutions of the copolymers in dioxane were examined for their photoluminescence properties.

Citation Download Citation

D. Bogdal, M. Pajda, Jan Pielichowski, André-Jean Attias, and J. Fave "Development of carbazole and bipyridine copolymers as novel photorefractive materials", Proc. SPIE 6252, Holography 2005: International Conference on Holography, Optical Recording, and Processing of Information, 62520K (9 June 2006); https://doi.org/10.1117/12.676785

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