Photonics of boron fluoride and zinc dipyrromethene complexes

Iuliia V. Aksenova; Alexander A. Prokopenko; Rimma T. Kuznetsova; Georgy V. Mayer; Natalia A. Bumagina; Mikhail B. Berezin

doi:10.1117/12.2305471

16 April 2018 Photonics of boron fluoride and zinc dipyrromethene complexes

Iuliia V. Aksenova, Alexander A. Prokopenko, Rimma T. Kuznetsova, Georgy V. Mayer, Natalia A. Bumagina, Mikhail B. Berezin

Author Affiliations +

Proceedings Volume 10614, International Conference on Atomic and Molecular Pulsed Lasers XIII; 106142A (2018) https://doi.org/10.1117/12.2305471
Event: XIII International Conference on Atomic and Molecular Pulsed Lasers, 2017, Tomsk, Russia

Abstract

Spectral, photophysical, photochemical characteristics for mononuclear and binuclear dipyrromethenes in complexes with BF₂ (BODIPY), bis-BODIPY and bis-helicates ([Zn₂(L)₂]) are described. The role of substituents (type and location in the ligand) and the medium in which dipyrromethene complexes are placed (solvents, solid-state matrices), the effect of different complexing agents (p- and d-elements) on the photonics of the complexes are discussed. The results of studying the lasing and photochemical properties of complexes under the action of laser irradiation are presented. In addition, for the described complexes the stability in the ground and excited states in protic media are estimated. Based on the analysis of the results discussed possibilities of practical application of these compounds to creating various optical devices.

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Iuliia V. Aksenova, Alexander A. Prokopenko, Rimma T. Kuznetsova, Georgy V. Mayer, Natalia A. Bumagina, and Mikhail B. Berezin "Photonics of boron fluoride and zinc dipyrromethene complexes", Proc. SPIE 10614, International Conference on Atomic and Molecular Pulsed Lasers XIII, 106142A (16 April 2018); https://doi.org/10.1117/12.2305471

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