Paper
17 May 2019 Fiber-lasers for coherent Raman detection of toxic chemical hazards
N. Coluccelli, A. Gambetta, E. Vicentini, P. Laporta, K. McEwan, C. R. Howle
Author Affiliations +
Abstract
We report on a fiber-format laser system for Fourier-transform coherent anti-Stokes Raman spectroscopy (FT-CARS) of toxic chemical hazards, such as chemical warfare agents (CWAs). The system is based on ytterbium-fiber technology featuring ultra-broad spectral coverage and high-sensitivity. High-quality CARS spectra with maximum Raman shifts of 3000 cm-1 and signal-to-noise ratio >200 for observation times of 160 μs are measured; a detection limit of one part per thousand is demonstrated with a cyanide/water solution. The system was developed as the basis for a highly accurate, sensitive, reliable and portable device for the real time detection of water contaminants and deposited CWAs at trace levels.
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N. Coluccelli, A. Gambetta, E. Vicentini, P. Laporta, K. McEwan, and C. R. Howle "Fiber-lasers for coherent Raman detection of toxic chemical hazards", Proc. SPIE 11010, Chemical, Biological, Radiological, Nuclear, and Explosives (CBRNE) Sensing XX, 1101015 (17 May 2019); https://doi.org/10.1117/12.2518847
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KEYWORDS
Raman spectroscopy

Interferometers

Spectroscopy

Amplifiers

Fourier transforms

Chemical weapons

Cyanide

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