Presentation + Paper
1 August 2021 Controlling polymorphism of metal-organic frameworks
Author Affiliations +
Abstract
Nonlinear optical (NLO) materials have attracted considerable attention due to their potential applications for wavelength converters and electro-optical modulators. One way to fabricate SHG materials is to align asymmetric organic dyes with high second-order hyperpolarizability constants. Here, we demonstrate one-dimensional alignment of asymmetric organic dyes in pores of metal-organic framework (MOF). MOF with Kagome-type lattice was synthesized to encapsulate the organic dyes in its one-dimensional pores. The organic dyes were oriented along with the onedimensional pores, which was confirmed by fluorescence under linearly-polarized excitation light.
Conference Presentation
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Kenji Hirai, Atsushi Nagahashi, Taisei Kitagawa, and Hiroshi Uji-i "Controlling polymorphism of metal-organic frameworks", Proc. SPIE 11795, Metamaterials, Metadevices, and Metasystems 2021, 117950M (1 August 2021); https://doi.org/10.1117/12.2593174
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KEYWORDS
Crystals

Absorption

Zinc

Scanning electron microscopy

Solids

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