Fourier transform infrared and Raman study of metal carbonyl clusters: distinction of covalent and dative metal-metal bonds

Steven M. Barnett; Stephane H.R. Brienne; Ian S. Butler; Frederick W.B. Einstein; Mike C. Jennings; Jonathan L. Male; Roland K. Pomeroy

doi:10.1117/12.166719

31 January 1994 Fourier transform infrared and Raman study of metal carbonyl clusters: distinction of covalent and dative metal-metal bonds

Steven M. Barnett, Stephane H.R. Brienne, Ian S. Butler, Frederick W.B. Einstein, Mike C. Jennings, Jonathan L. Male, Roland K. Pomeroy

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Proceedings Volume 2089, 9th International Conference on Fourier Transform Spectroscopy; (1994) https://doi.org/10.1117/12.166719
Event: Fourier Transform Spectroscopy: Ninth International Conference, 1993, Calgary, Canada

Abstract

Fourier transform infrared and Raman spectroscopy have been used to investigate a number of metal carbonyl clusters involving bonds between osmium and other transition metals. The distinction of covalent and dative metal-metal bonds is discussed with an emphasis on the polarization techniques used in this analysis. The application of permutation theory in the spectroscopic analysis of LM(CO)₅ complexes and its use in this analysis are presented.

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Steven M. Barnett, Stephane H.R. Brienne, Ian S. Butler, Frederick W.B. Einstein, Mike C. Jennings, Jonathan L. Male, and Roland K. Pomeroy "Fourier transform infrared and Raman study of metal carbonyl clusters: distinction of covalent and dative metal-metal bonds", Proc. SPIE 2089, 9th International Conference on Fourier Transform Spectroscopy, (31 January 1994); https://doi.org/10.1117/12.166719

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