Fourier transform infrared study of the Van der Waals molecules between alkyl chlorides and hydrogen chloride in liquified argon

Benjamin J. van der Veken; Wouter Herrebout

doi:10.1117/12.166581

31 January 1994 Fourier transform infrared study of the Van der Waals molecules between alkyl chlorides and hydrogen chloride in liquified argon

Benjamin J. van der Veken, Wouter Herrebout

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Proceedings Volume 2089, 9th International Conference on Fourier Transform Spectroscopy; (1994) https://doi.org/10.1117/12.166581
Event: Fourier Transform Spectroscopy: Ninth International Conference, 1993, Calgary, Canada

Abstract

Mid-IR spectra (4000 - 400 cm^-1) of mixtures of HCl with methyl-d₃, ethyl- d₅, n-propyl, isopropyl-d₇ or t-butyl chloride, dissolved in liquified argon (95 - 117 K) and liquified krypton (122 - 148 K) have been investigated. In all cases the formation of a 1:1 Van der Waals molecule between HCl and the alkyl chloride was observed. At higher concentrations, a new absorption band, due to a 1:2 complex (RCl)(DOT)(HCl)₂ was found. Ab initio structural calculations at the RHF/6-31G^** level show the complexes have an approximate L-shape.

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Benjamin J. van der Veken and Wouter Herrebout "Fourier transform infrared study of the Van der Waals molecules between alkyl chlorides and hydrogen chloride in liquified argon", Proc. SPIE 2089, 9th International Conference on Fourier Transform Spectroscopy, (31 January 1994); https://doi.org/10.1117/12.166581

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