Conformational relaxation phenomena of amino derivatives of fluorene

J. R. Heldt; J. Heldt; M. Jozefowicz; K. A. Kozyra; T. Redzimski

doi:10.1117/12.629484

1 June 2005 Conformational relaxation phenomena of amino derivatives of fluorene

J. R. Heldt, J. Heldt, M. Jozefowicz, K. A. Kozyra, T. Redzimski

Proceedings Volume 5849, Fifth Workshop on Atomic and Molecular Physics; (2005) https://doi.org/10.1117/12.629484
Event: Fifth Workshop on Atomic and Molecular Physics, 2004, Jurata, Poland

Abstract

The absorption and fluorescence spectra of 2-methylaminofluorenone (I) 2-dimethylaminofluorenone (II) and 2-dimethylamino-9-phenyl(4'-dimethylamino)-9-fluorenol (III) were determined in variety of solvents with different polarities. The Marcus theory has been applied to obtain the outer-sphere reorganization energy, λ_outer, and the innersphere reorganization energies: λ_i^* and λ_i associated with the vibrations for which hv<kT and hv>kT respectively.

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J. R. Heldt, J. Heldt, M. Jozefowicz, K. A. Kozyra, and T. Redzimski "Conformational relaxation phenomena of amino derivatives of fluorene", Proc. SPIE 5849, Fifth Workshop on Atomic and Molecular Physics, (1 June 2005); https://doi.org/10.1117/12.629484

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