Paper
13 September 1996 Low-temperature photoluminescence characterization of impurity-doped GaAs and silicides prepared by molecular beam epitaxy, high-energy ion implantation, and combined ion-beam and molecular beam epi
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Abstract
By using molecular beam epitaxy (MBE) technology, one can now fabricate routinely ultra-pure GaAs and Si layers with the background residual impurity concentration lower than approximately 1 by 1014 cm-3. We incorporated mass-separated impurities into these layers by means of high-energy ion-implantation (HE-I2) and low-energy ion beam impinging during MBE growth (CIBMBE). Low-temperature (2K) photoluminescence (PL) spectra from acceptor-doped GaAs layers prepared by HE-I2 and CIBMBE methods revealed that multiple shallow emission levels are formed with increasing net hole concentration, NA-ND. These emissions were theoretically interpreted as the pairs between ground- and excited-states acceptors. The absence of these energy levels in the conventional specimens was attributed to a strong optical compensation effect induced by an extremely small amount of shallow donors that were accidentally introduced during sample preparation. The majority of these energy levels were found to present strong red or blue energy-shifting with increasing NA-ND. These PL features were confirmed to be used for the determination of NA-ND and compensation ratio totally by an optical method. High-dose incorporation of Fe atoms into Si substrates was carried out by HE-I2 method for the synthesis of beta-FeSi2. In 2K-PL spectra, one noticed strong edge-emission from beta- FeSi2, indicating that HE-I2 method is powerful to synthesize high quality silicides.
© (1996) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Yunosuke Makita "Low-temperature photoluminescence characterization of impurity-doped GaAs and silicides prepared by molecular beam epitaxy, high-energy ion implantation, and combined ion-beam and molecular beam epi", Proc. SPIE 2877, Optical Characterization Techniques for High-Performance Microelectronic Device Manufacturing III, (13 September 1996); https://doi.org/10.1117/12.250922
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KEYWORDS
Gallium arsenide

Chemical species

Doping

Magnesium

Ion beams

Beryllium

Calcium

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