The Mg-doped near stoichiometric LiNbO3 crystal of 30mm in diameter and 20mm in length was grown with top seed solution growth (TSSG) method from Li-rich melt doped with 1mol% MgO. Compared with nondoped congruent LiNbO3 crystal, fundamental absorption edge of the as-grown crystal shifted to shorter wavelength and position of the OH- infrared absorption peak also changed distinctly. All these results indicated that composition of the as-grown crystal was near-stoichiometric.
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